The payment modes available to your employees depends on multiple factors. 'Default' payment mode means the payment mode which will be auto-filled whenever an employee tries to create an expense. (on web app, mobile app, Gmail extension, Outlook add-in, Slack, or via email forwarding)

Please Note: To change any default already set, you will have to contact the CS support team at [email protected].

If your Organization uses Corporate Cards, you can set 'Corporate Card' as the default payment mode for all employees with a Corporate Card assigned to them. Employees with no Corporate Card assigned to them will have Personal Card/Cash as the default payment mode. The admin's view will look like this:
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The admin can also ask the support team to set Corporate Card as the only payment mode. What this essentially does is remove 'Personal Card/Cash' completely.* The admin's view will look like this:
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If the Corporate Card section is disabled for your Organization, 'Personal Card/Cash' will automatically become the default payment mode. The admin's view will look like this:

Mileage and per diem expenses are reimbursable by default. The employees will not see any payment mode for them as the expenses are by default 'Personal Card/Cash'.*

Only those employees who have advances issued to them will see advance as a payment mode in their expense forms. (include mileage and per diem)